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In the boys' school of Seika High, a trailblazing leader has emerged in the form of Misaki Ayuzawa, the first-ever female student council president. With her unwavering dedication and unshakeable integrity, she has transformed the school's atmosphere, earning her the nickname "Demon President" among the male student body. However, her tough exterior belies a softer side, as she secretly works at a maid cafe to support her family.

When Misaki stumbles upon Takumi Usui, the school's most popular and enigmatic student, rejecting a love confession, she's compelled to reprimand him for his careless behavior. But Usui remains unapologetic, leaving Misaki perplexed. The two cross paths again, this time at the maid cafe, where Misaki's secret life is exposed. Determined to protect her reputation, she vows to keep Usui at arm's length. Yet, the cunning boy continues to frequent the cafe, observing and teasing Misaki with an air of mystery.

As Usui's visits become more frequent, Misaki finds herself torn between her duty as president and her growing fascination with the enigmatic boy. Will Usui's persistent meddling ultimately unravel Misaki's carefully constructed persona, or will she find a way to keep her secret safe?